Fragmentation of chloroperoxides: hypochlorite-mediated dehydration of hydroperoxyacetals to esters.
نویسندگان
چکیده
Hypochlorites efficently dehydrate hydroperoxyacetals to furnish the corresponding esters. The reaction, which can be accomplished with stoichometric Ca(OCl)(2) or with catalytic amounts of t-BuOCl, appears to involve formation and heterolytic fragmentation of secondary chloroperoxides, species not previously described in solution chemistry.
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عنوان ژورنال:
- Tetrahedron letters
دوره 51 42 شماره
صفحات -
تاریخ انتشار 2010